RT info:eu-repo/semantics/article T1 Star-branched polyamides as the matrix in thermoplastic composites A1 Núñez Carrero, Karina Carla A1 Herrero Villar, Manuel A1 Asensio Valentín, María A1 Guerrero, Julia A1 Merino Senovilla, Juan Carlos A1 Pastor Barajas, José María K1 Polyamide K1 Poliamidas K1 Polymers K1 Thermoplastic composites K1 Thermoplastics K1 Termoplásticos K1 Welding K1 Chemistry K1 2206.10 Polímeros K1 3316.14 Soldaduras K1 3312 Tecnología de Materiales K1 23 Química AB The aim of this study is the preparation of star-shaped branched polyamides (sPA6) with low melt viscosity, but also with improved mechanical properties by reactive extrusion. This configuration has been obtained by grafting a tri-functional, three-armed molecule: 5-aminoisophthalic-acid, used as a linking agent (LA). The balance between the fluidity, polarity and mechanical properties of sPA6s is the reason why these materials have been investigated for the impregnation of fabrics in the manufacture of thermoplastic composites. For these impregnation processes, the low viscosity of the melt has allowed the processing parameters (temperature, pressure and time) to be reduced, and its new microstructure has allowed the mechanical properties of virgin thermoplastic resins to be maintained. A significant improvement in the ultrasonic welding processes of the composites was also found when an energy director based on these materials was applied at the interface. In this work, an exhaustive microstructural characterization of the obtained sPAs is presented and related to the final properties of the composites obtained by film stacking. PB MDPI SN 2073-4360 YR 2022 FD 2022 LK https://uvadoc.uva.es/handle/10324/62263 UL https://uvadoc.uva.es/handle/10324/62263 LA eng NO Polymers, 2022, Vol. 14, Nº. 5, 942 NO Producción Científica DS UVaDOC RD 22-nov-2024