RT info:eu-repo/semantics/article T1 Glucosinolates as markers of the origin and harvesting period for discrimination of bee pollen by UPLC-MS/MS A1 Ares Sacristán, Ana María A1 Tapia García, Jesús Alberto A1 González Porto, Amelia Virginia A1 Higes Pascual, Mariano A1 Martín Hernández, Raquel A1 Bernal del Nozal, José K1 Authentication K1 Bee pollen K1 Polen K1 Bioactive compounds K1 Compuestos bioactivos K1 Food - Analysis K1 Alimentos - Análisis K1 Food - Quality K1 Alimentos - Calidad - Control K1 Harvesting K1 Cultivos K1 Glucosinolates K1 Food science K1 2301 Química Analítica K1 3206 Ciencias de la Nutrición K1 3309 Tecnología de Los Alimentos AB Bee pollen is currently one of the most commonly consumed food supplements, as it is considered to be a good source of bioactive substances and energy. It contains various health-promoting compounds, such as proteins, amino acids, lipids, as well as glucosinolates. In the present study, the glucosinolate content was determined, by means of ultra-performance liquid chromatography coupled to a quadrupole time-of-flight mass detector, in 72 bee pollen samples from four different apiaries in Guadalajara (Spain), harvested in three different periods. In addition, 11 commercial multifloral samples from different Spanish regions were also analyzed. The aim was to verify the suitability of these compounds as biomarkers of their geographical origin, and to test their potential for distinguishing the harvesting period. By means of a canonical discriminant analysis, it was possible to differentiate the apiary of origin of most of the samples, and these could also be clearly differentiated from the commercial ones, simply as a result of the glucosinolate content. In addition, it was also demonstrated for the first time that bee pollen samples were capable of being differentiated according to the time of harvesting and their glucosinolate content. PB MDPI SN 2304-8158 YR 2022 FD 2022 LK https://uvadoc.uva.es/handle/10324/62750 UL https://uvadoc.uva.es/handle/10324/62750 LA eng NO Foods, 2022, Vol. 11, Nº. 10, 1446 NO Producción Científica DS UVaDOC RD 07-ago-2024