RT info:eu-repo/semantics/article T1 A feasibility study on the bioconversion of CO2 and H2 to biomethane by gas sparging through polymeric membranes A1 Díaz Villalobos, Israel A1 Pérez, Carlos A1 Alfaro, Natalia A1 Fernández-Polanco Fernández de Moreda, Fernando K1 biomethane K1 biogas upgrading K1 hydrogenotrophic archaea K1 MBR K1 methanation K1 3303 Ingeniería y Tecnología Químicas K1 3322.05 Fuentes no Convencionales de Energía K1 3308 Ingeniería y Tecnología del Medio Ambiente AB In this study, the potential of a pilot hollow-fiber membrane bioreactor for the conversion of H2 and CO2 to CH4 was evaluated. The system transformed 95% of H2 and CO2 fed at a maximum loading rate of 40.2(m_(H_2)^3)⁄(m_R^3 d) and produced 0.22 m3 of CH4 per m3 of H2 fed at thermophilic conditions. H2 mass transfer to the liquid phase was identified as the limiting step for the conversion, and kLa values of 430h-1 were reached in the bioreactor by sparging gas through the membrane module. A simulation showed that the bioreactor could upgrade biogas at a rate of 25m^3⁄(m_R^3 d), increasing the CH4 concentration from 60 to 95%v. This proof-of-concept study verified that gas sparging through a membrane module can efficiently transfer H2 from gas to liquid phase and that the conversion of H2 and CO2 to biomethane is feasible on a pilot scale at noteworthy load rates. PB Elsevier SN 0960-8524 YR 2015 FD 2015 LK https://uvadoc.uva.es/handle/10324/63707 UL https://uvadoc.uva.es/handle/10324/63707 LA spa NO Bioresource Technology, Junio 2015, vol 185, p. 246-253 NO Producción Científica DS UVaDOC RD 24-nov-2024