RT info:eu-repo/semantics/article
T1 MgH Rydberg series: Transition energies from electron propagator theory and oscillator strengths from the molecular quantum defect orbital method
A1 Corzo, H.H.
A1 Ortiz, J.V.
A1 Velasco Sanz, Ana María
A1 Lavín Puente, María del Carmen
K1 MgH Rydberg Series
AB Vertical excitation energies belonging to several Rydberg series of MgH have been inferred from 3+ electron-propagator calculations of the electron affinities of MgH+ and are in close agreement with experiment. Many electronically excited states with n>3 are reported for the first time and new insight is given on the assignment of several Rydberg series. Valence and Rydberg excited states of MgH are distinguished respectively by high and low pole strengths corresponding to Dyson orbitals of electron attachment to the cation. By applying the Molecular Quantum Defect Orbital method, oscillator strengths for electronic transitions involving Rydberg states also have been determined.
PB Elsevier
SN 0022-4073
YR 2018
FD 2018
LK https://uvadoc.uva.es/handle/10324/64805
UL https://uvadoc.uva.es/handle/10324/64805
LA eng
NO Journal of Quantitative Spectroscopy & Radiative Transfer 206 (2018) 323–327
NO Producción Científica
DS UVaDOC
RD 22-dic-2024