RT info:eu-repo/semantics/article
T1 Understanding the color change of the solutions of Cp2TiCl upon addition of water
A1 Thiessen, Tanner
A1 Sidhu, Jaspreet
A1 McIndoe, J. Scott
A1 Rodríguez‐García, Ignacio
A1 Rosales Martínez, Antonio
A1 Jaraíz Maldonado, Martín
A1 Enríquez Giraudo, María Lourdes
A1 mcindoe
K1 hydrogen atom transfer reagent
K1 radic
K1 colorimetric indicator
K1 radical chemistry
K1 titanocede
AB Reduction of red bis (cyclopentadienyl)titanium (IV) dichloride (Cp2TiCl2)with manganese dust in dry THF produces a green solution that turns deepblue upon the addition of traces of water. Mass spectrometric analysis andDFT calculations have been performed to achieve a better understanding ofthe species that may be present after the interaction of water with reducedCp2TiCl2. The deep blue solution provides a handy visual indicator for thequalitative determination of water in THF
PB Wiley
SN 0268-2605
YR 2022
FD 2022
LK https://uvadoc.uva.es/handle/10324/64851
UL https://uvadoc.uva.es/handle/10324/64851
LA eng
NO Appl Organomet Chem.2023;37:c6979
NO Producción Científica
DS UVaDOC
RD 07-ago-2024