RT info:eu-repo/semantics/article
T1 Design and recognition of cucurbituril-secured platinum-bound oligopeptides
A1 Barbero San Juan, Héctor
A1 Masson, Eric
AB Platinum terpyridyl complexes, stacked on top of one another and secured as dimers with cucurbit[8]uril (CB[8]) in aqueous medium, were functionalized quantitatively and in situ with a pair of pentapeptides Phe-(Gly)3-Cys by grafting their cysteine residues to the Pt centers. The resulting CB[8]·(Pt·peptide)2 assemblies were used to target secondary hosts CB[7] and CB[8] via their pair of phenylalanine residues, again in situ. A series of well-defined architectures, including a supramolecular “pendant necklace” with hybrid head-to-head and head-to-tail arrangements inside CB[8], were obtained during the self-sorting process after combining only 3 or 4 simple building units.
PB Royal Society of Chemistry
SN 2041-6520
YR 2021
FD 2021
LK https://uvadoc.uva.es/handle/10324/65374
UL https://uvadoc.uva.es/handle/10324/65374
LA eng
NO Chem. Sci., 2021, 12, 9962
NO Producción Científica
DS UVaDOC
RD 22-dic-2024