RT info:eu-repo/semantics/article
T1 Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
A1 Ferrero, Sergio
A1 Barbero San Juan, Héctor
A1 Álvarez González, Celedonio Manuel
AB The main purpose of this video is to show 6 reaction steps of a convergent synthesis and prepare a complex molecule containing up to three nonplanar polyaromatic units, which are two corannulene moieties and a racemic hexahelicene linking them. The compound described in this work is a good host for fullerenes. Several common organic reactions, such as free-radical reactions, C-C coupling or click chemistry, are employed demonstrating the versatility of functionalization that this compound can accept. All of these reactions work for planar aromatic molecules. With subtle modifications, it is possible to achieve similar results for nonplanar polyaromatic compounds.
PB MyJove Corp.
YR 2016
FD 2016
LK https://uvadoc.uva.es/handle/10324/65377
UL https://uvadoc.uva.es/handle/10324/65377
LA eng
NO J. Vis. Exp. (115), e53954
NO Producción Científica
DS UVaDOC
RD 23-dic-2024