RT info:eu-repo/semantics/article
T1 Dibenzomethanopentacene‐Based Polymers of Intrinsic Microporosity for Use in Gas‐Separation Membranes
A1 Chen, Jie
A1 Longo, Mariagiulia
A1 Fuoco, Alessio
A1 Esposito, Elisa
A1 Monteleone, Marcello
A1 Carolus Jansen, Johannes
A1 McKeown, Neil B.
A1 Comesaña Gándara, Bibiana
AB Dibenzomethanopentacene (DBMP) is shown to be a useful structural component for makingPolymers of Intrinsic Microporosity (PIMs) with promise for making efficient membranes for gas separations. DBMP-based monomers for PIMs are readily prepared using a Diels–Alder reaction between 2,3-dimethoxyanthracene and norbornadiene as the key synthetic step. Compared to date for the archetypal PIM-1, the  incorporation of DBMP simultaneously enhances both gas permeability and the ideal selectivity for one gas over another. Hence, both ideal and mixed gas permeabilitydata for DBMP-rich co-polymers and an amidoxime modified PIM are close to the current Robesonupper bounds, which define the state-of-the-art for the trade-off between permeability and selectivity, forseveral important gas pairs. Furthermore, long-term studies (over 3 years) reveal that the reduction in gaspermeabilities on ageing is less for DBMP-containing PIMs relative to that for other high performing PIMs,which is an attractive property for the fabrication of membranes for efficient gas separations.
PB Wiley-VCHGm
SN 1433-7851
YR 2023
FD 2023
LK https://uvadoc.uva.es/handle/10324/65424
UL https://uvadoc.uva.es/handle/10324/65424
LA eng
NO Angew. Chem. Int. Ed.2023,62,e2022152
NO Producción Científica
DS UVaDOC
RD 07-ago-2024