RT info:eu-repo/semantics/article
T1 Efficiency of Acid‐ and Mercury‐Catalyzed Cyclization Reactions in the Synthesis of Tetrahydrofurans from Allylsilyl Alcohols
A1 Pulido Pelaz, Francisco José
A1 Barbero Pérez, María Asunción
A1 Val, Patricia
A1 Diez de la Varga, Alberto
A1 González Ortega, Alfonso
AB The scope of the acid-catalyzed and mercury-catalyzed cyclization reactions of allylsilyl alcohols is described. This methodology has been found to be an efficient approach to the synthesis of highly substituted tetrahydrofurans. The stereoselectivity of the cyclization is dependent both on the substitution of the starting alcohol and on the catalyst. A plausible mechanism has been proposed that is consistent with the results.
PB Wiley-VCH Verlag GmbH
SN 1434-193X
YR 2012
FD 2012
LK https://uvadoc.uva.es/handle/10324/65950
UL https://uvadoc.uva.es/handle/10324/65950
LA eng
NO Eur. J. Org. Chem. 2012, 5350–5356
NO Producción Científica
DS UVaDOC
RD 22-nov-2024