RT info:eu-repo/semantics/article
T1 Thermodynamics of Mixtures Containing a Strongly Polar Compound. 9. Liquid−Liquid Equilibria for ε-Caprolactam + Selected Alkanes
A1 Alonso Gómez, Víctor
A1 Alonso de Miguel, Iván
A1 Mozo, Ismael
A1 González López, Juan Antonio Mariano
A1 García de la Fuente, Isaías Laudelino
A1 Cobos Hernández, José Carlos
K1 Termodinámica
K1 Equilibrio Líquido Líquido
K1 Caprolactano
K1 Alcanos
AB The coexistence curves of the liquid-liquid equilibria (LLE) for systems of  -caprolactam with  heptane, octane,  nonane, decane or 2,2,4-trimethylpentane have been determined by the method of the critical opalescence using a laser scattering technique. All the curves show an upper critical solution temperature (UCST), have a rather horizontal top and their symmetry depends on the size of the alkane. The UCST increases almost linearly with the chain length of the n-alkane. For the octane mixture, the UCST is lower than for the solution including 2,2,4-trimethylpentane.
PB ACS Publications
YR 2010
FD 2010
LK https://uvadoc.uva.es/handle/10324/66096
UL https://uvadoc.uva.es/handle/10324/66096
LA eng
NO Journal of Chemical & Engineering Data, 2010, 55 (6), 2263-2266
NO Producción Científica
DS UVaDOC
RD 27-nov-2024