RT info:eu-repo/semantics/article
T1 Dielectric and refractive index measurements for the systems 1-pentanol + octane, or + dibutyl ether or for dibutyl ether + octane at different temperatures
A1 Alonso Gómez, Víctor
A1 González López, Juan Antonio Mariano
A1 García de la Fuente, Isaías Laudelino
A1 Cobos Hernández, José Carlos
AB Relative permittivities,  , and refractive indixes,  , have been measured at (288.15-308.15) K and (293.15-303.15) K, respectively, for the mixtures 1-pentanol + octane, or + dibutyl ether and dibutyl ether + octane. These data have been used, together with density measurements available in the literature, to determine the correlation factor,  , for the studied systems according to the Kirkwood-Fröhlich equations. Results show that the existence of cyclic species of 1-pentanol are predominant at low concentrations of this alkanol when is mixed with octane. These species are broken in large extent by the more active molecules of oxaalkane in the dibutyl ether mixtures, which is in agreement with calorimetric data. The dibutyl ether + octane system does not show meaningful structure. These conclusions are confirmed by values of the molar polarization and by the temperature dependence of  . The empirical expressions of Lorentz-Lorenz, Wiener, Heller, Gladstone-Dale and Newton correlate well the   data.
YR 2012
FD 2012
LK https://uvadoc.uva.es/handle/10324/66121
UL https://uvadoc.uva.es/handle/10324/66121
LA eng
NO Dielectric and refractive index measurements for the systems 1-pentanol + octane, or + dibutyl ether or for dibutyl ether + octane at different temperatures
DS UVaDOC
RD 20-may-2024