RT info:eu-repo/semantics/article T1 Improving the anaerobic digestion process of wine lees by the addition of microparticles A1 García Álvaro, Alfonso A1 Ruiz Palomar, César A1 Hermosilla Redondo, María Daphne A1 Gasco Guerrero, Antonio María A1 Muñoz Torre, Raúl A1 Godos Crespo, Ignacio de K1 Biogas K1 Wine lees K1 Wine K1 Graphite K1 Grafito K1 Magnetite K1 Phenols K1 Fenoles K1 Biomass energy K1 Energía de biomasa K1 Anaerobic digestion K1 Organic wastes - Recycling K1 Residuos orgánicos - Reciclaje K1 Renewable energy resources K1 Energias renovables K1 3309.29 Vino K1 3309 Tecnología de Los Alimentos K1 2510.91 Recursos Renovables AB Wine lee generation, a by-product of the wine industry, implies economic challenges for producers in terms of management due to its high organic load and low pH value. Biological treatment based on controlled anaerobic digestion may emerge as a viable management alternative given its promising potential for biogas production thanks to the organic content of the substrate. However, the complex properties of wine lees may lead to microbial activity inhibition and process kinetics failure. Various solutions have already been explored, including co-digestion with other substrates, or the application of different pretreatments, to mitigate the effects of the accumulation of phenolic compounds, volatile fatty acids, antioxidants, or the acidic pH value of the medium. In this study, laboratory-scale batch reactors were established, adding iron- (magnetite) or carbon (graphite)-based microparticles to assess their impact on the kinetics of the process. The results demonstrate a significant improvement of 35% in the potential production of biomethane after four days of operation with graphite particles and 42% after five days using magnetite particles. Methane production rates, as determined by the Gompertz model, were 45.38 and 46.54 mL CH4∙gVS−1∙d−1 for the application of graphite and magnetite microparticles to the medium, respectively, compared to the value of 33.46 mL CH4∙gVS−1∙d−1 for the control trial, confirming kinetic process improvements of 36% and 39%, respectively. Evidences of the acceleration of the methanogenesis phase were detected along the essays; however, the strong inhibition mediated by the carboxylate accumulation was not avoided in any of the tested conditions. PB MDPI SN 2073-4441 YR 2023 FD 2023 LK https://uvadoc.uva.es/handle/10324/67224 UL https://uvadoc.uva.es/handle/10324/67224 LA eng NO Water, 2024, Vol. 16, Nº. 1, 101 NO Producción Científica DS UVaDOC RD 12-sep-2024