RT info:eu-repo/semantics/article T1 Volumetric behaviour of (carbon dioxide + hydrocarbon) mixtures at high pressures A1 Zambrano, Johnny A1 Gómez-Soto, Franklin V. A1 Lozano Martín, Daniel A1 Martín González, María del Carmen A1 Segovia Puras, José Juan K1 Termodinámica K1 2213 Termodinámica AB The interest of oil industry in increasing heavy oil production has promoted the use of enhanced oil recovery techniques such as CO2 injection, which produce a decrease of oil viscosity and displacement of heavy oil from reservoir to surface. The design of these processes requires accurate data of densities, viscosities or surface tensions of (CO2 + hydrocarbon) mixtures in order to simulate the behaviour of these mixtures in the reservoir.An automated Anton Paar DMA HPM vibrating-tube densimeter was used to measure densities of this kind of mixtures, and a new mixture injection system, by means of two syringe pumps, was developed for the densimeter. The equipment operates at high pressure, which is controlled through a back pressure valve and a variable volume cylinder with a stepper motor. The estimated standard uncertainty of the density is ±0.9 kg m−3 at temperatures below 373.15 K and pressure range (0.1–140) MPa.In this paper, the densities of the mixtures (CO2 + n-decane), (CO2 + n-dodecane) and (CO2 + squalane) are reported at T = (283.15–393.15) K and p = (10–100) MPa. PB Elsevier SN 0896-8446 YR 2016 FD 2016 LK https://uvadoc.uva.es/handle/10324/69219 UL https://uvadoc.uva.es/handle/10324/69219 LA spa NO The Journal of Supercritical Fluids, 2016, vol. 110, p. 103-109 DS UVaDOC RD 21-nov-2024