RT info:eu-repo/semantics/article
T1 Solid–Liquid Equilibria for the Binary Systems Naphthalene or Biphenyl + 1-Tetradecanol or + 1-Hexadecanol
A1 Sanz del Soto, Luis Felipe
A1 González López, Juan Antonio Mariano
A1 Hevia de los Mozos, Luis Fernando
A1 García de la Fuente, Isaías Laudelino
A1 Cobos Hernández, José Carlos
K1 Termodinámica
K1 2213 Termodinámica
AB A differential scanning calorimetric technique has been used to obtain solid-liquid equilibrium temperatures for the mixtures naphthalene or biphenyl + 1-tetradecanol, or + 1-hexadecanol. All the systems show a simple eutectic point, whose final composition was determined by means of the Tamman’s plots using the needed values of the eutectic heat and of the heat of melting, which are also reported. DISQUAC interaction parameters for the OH/aromatic contacts in the selected systems are given. The present experimental SLE phase diagrams are similarly described by DISQUAC and UNIFAC (Dortmund) models. However, the comparison of DISQUAC and UNIFAC results for systems involving naphthalene and shorter 1-alkanols (methanol-1-octanol) reveals that the temperature dependence of the interaction parameters is more suitable in DISQUAC. The systems are also investigated in terms of the concentration-concentration structure factor. It is shown that the positive deviations from the Raoult’s law of the studied solutions become weaker when the homocoordination decreases.
PB Springer
SN 0095-9782
YR 2023
FD 2023
LK https://uvadoc.uva.es/handle/10324/69222
UL https://uvadoc.uva.es/handle/10324/69222
LA spa
NO Journal of Solution Chemistry, 2024, 53, 160-181
DS UVaDOC
RD 01-sep-2024