RT info:eu-repo/semantics/article T1 Membrane materials for biogas purification and upgrading: Fundamentals, recent advances and challenges A1 Rodero Raya, María del Rosario A1 Muñoz Torre, Raúl A1 González Sánchez, Armando A1 Ruiz, Héctor A. A1 Quijano Govantes, Guillermo K1 Biogas separation K1 Carbon dioxide removal K1 Biofuels K1 Biomethane K1 Membrane performance K1 3303 Ingeniería y Tecnología Químicas K1 3322.05 Fuentes no Convencionales de Energía AB Biogas from the anaerobic digestion of organic waste stands as a renewable energy source with a large potential to reduce the global dependence on fossil fuels. Biogas applications as a vehicle fuel or natural gas substitute requires the separation of the main biogas components, namely methane and carbon dioxide. Such biogas separation is also necessary for valorizing carbon dioxide, which is a valuable molecule in food and beverage industries, chemical synthesis and greenhouses, among other industrial activities. While most biological technologies focused on biogas separation are still in the development phase, the use of membranes for this purpose has increased exponentially in the last decade due to its efficiency, compact design, economic feasibility, and easy scalability. This article provides a comprehensive overview of the current state of membrane technology, focusing on both fundamental principles and the latest advancements in membrane systems for biogas purification and upgrading. 6FDA-based polyimides and polymers of intrinsic microporosity offer promising prospects for advancing membrane technologies used in biogas upgrading. The incorporation of fillers, such as zeolites and metal-organic frameworks, into a polymer matrix to create mixed matrix membranes (MMMs) significantly enhances the overall performance (CO2 permeabilities up to 18,000 Barrer and CO2/CH4 selectivity values up to 85) and functionality of the membrane. However, the key challenges for MMMs remain in fabricating defect-free membranes with high CO2/CH4 selectivity and ensuring long-term stability over several months. PB Elsevier SN 2213-3437 YR 2024 FD 2024 LK https://uvadoc.uva.es/handle/10324/73605 UL https://uvadoc.uva.es/handle/10324/73605 LA eng NO Journal of Environmental Chemical Engineering, octubre 2024, vol. 12, n. 5, 114106 NO Producción Científica DS UVaDOC RD 05-abr-2025