RT info:eu-repo/semantics/article T1 Treatment of mature landfill leachate by electrocoagulation followed by Fenton or UVA-LED photo-Fenton processes A1 Tejera, Javier A1 Hermosilla, Daphne A1 Gascó, Antonio A1 Miranda, Rubén A1 Negro, Carlos A1 Blanco, Ángeles A1 Alonso Gómez, Víctor AB The main objective of this study is to optimize a two-step treatment for mature landfill leachate consisting of electrocoagulation (EC) followed by Fenton or UVA-LED photo-Fenton processes aiming to provide a more efficient and feasible alternative treatment strategy that also increases biodegradability and decreases conductivity. Although 5 mA cm−2 EC is cheaper than 10 mA cm−2 EC per kg of removed COD (0.63 vs. 0.89 € kgCOD−1), it achieved the half total COD removal (13% compared to 26%), and the low residual iron concentration (100 mg L−1) that remained at the end of the process made necessary a long treatment time to perform the posterior Fenton (48 h) or UVA-LED photo-Fenton (6 h) process. When EC was performed at 10 mA cm−2, the residual iron concentration (220 mg L−1) was high enough to reduce treatment time by one half for both Fenton processes. Consequently, treatment cost decreases from 5.91 to 3.48 € kgCOD−1 for the EC + UVA-LED photo-Fenton ([H2O2]/COD = 1.063) treatment combination; whereas it slightly decreases from 1.68 to 1.61 € kgCOD−1 for the alternative EC + conventional Fenton combination. In both cases, total COD removal was around 87%. In addition, SUVA removal was >40%, conductivity was reduced about 20–30%, and biodegradability (BOD5/COD) increased over 0.3. SN 1876-1070 YR 2021 FD 2021-02 LK https://uvadoc.uva.es/handle/10324/74748 UL https://uvadoc.uva.es/handle/10324/74748 LA eng NO Journal of the Taiwan Institute of Chemical Engineers, 2021, Volume 119, Pages 33-44, DS UVaDOC RD 11-abr-2025