RT info:eu-repo/semantics/article
T1 Multitopic corannulene–porphyrin hosts for fullerenes: a three-layer scaffold for precisely designed supramolecular ensembles
A1 Álvarez Llorente, Nerea
A1 Stasyuk, Anton J.
A1 Diez De La Varga, Alberto
A1 Ferrero, Sergio
A1 Solà, Miquel
A1 Barbero San Juan, Héctor
A1 Álvarez González, Celedonio Manuel
K1 2303 Química Inorgánica
AB A method to synthesize cofacial dimeric porphyrins bearing eight corannulene units has been developed. It relies on the stability of octahedral CO-capped Ru(II) complexes linked by N-donor ligands. This specific arrangement provides an optimal scaffold to accommodate fullerenes by imposing corannulene groups at a precise distance and relative orientation. Their capabilities for C60 recognition have been thoroughly assessed, revealing that each system can encapsulate up to four guests, giving rise to a compact supramolecular van der Waals complex echoing a discrete donor–acceptor–donor trilayer offering significant potential properties for further exploitation.
PB ACS (American Chemical Society)
SN 1523-7060
YR 2024
FD 2024
LK https://uvadoc.uva.es/handle/10324/75064
UL https://uvadoc.uva.es/handle/10324/75064
LA eng
NO Organic Letters, 2025, vol. 17, n. 1, p. 357-362
NO Producción Científica
DS UVaDOC
RD 22-feb-2025