RT info:eu-repo/semantics/article
T1 Highly fluorescent 3-perylenyldiphenylphosphane compounds: An experimental and theoretical study
A1 Expósito, J. Emilio
A1 Lentijo, Sergio
A1 Aullón, Gabriel
A1 Bardají, Manuel
A1 Miguel, Jesús A.
AB The perylene derivative, 3-perylenyldiphenylphosphane (PPh2Per, 1), was prepared and used to synthesize the oxidized P(V) compounds A = PPh2Per (A = O (2); A = S (3)). Substitution reactions led to mononuclear gold(I) complexes [AuX(PPh2Per)] (X = Cl (4); X = C6F5 (5)), [AuX(S=PPh2Per)] (X = Cl (6); X = C6F5 (7)) and palladium(II) complexes trans-[Pd(C6F5)2(PPh2Per)2] (8). X-ray single crystal studies of compounds 5 and 7 confirmed the expected structures. The UV–Vis absorption spectra display intense peaks in the visible region with maxima from 454 to 461 nm. A DFT study was performed for the absorption spectra of ligands and complexes, showing that the lowest most intense transition is a HOMO → LUMO transition in the perylene core, although affected by functional group and metallic fragment. The ligands and their complexes are fluorescent in solution, due to the perylene fragment, showing an emission in the range 450–550 nm, with maxima from 467 to 472 nm. Quantum yield starts at 13 % for the phosphane and increases dramatically to the range of 63–87 % after oxidation or coordination to a metal fragment. This work illustrates how the PET effect can be used to recover the initial extremely intense emission of free unfunctionalized perylene ring system.
SN 0143-7208
YR 2025
FD 2025
LK https://uvadoc.uva.es/handle/10324/75803
UL https://uvadoc.uva.es/handle/10324/75803
LA eng
NO Dyes and Pigments 2025, 236, 112690 (8 páginas)
NO Producción Científica
DS UVaDOC
RD 07-jun-2025