RT info:eu-repo/semantics/article T1 Impact of hydrogen addition, up to 20 % (mol/mol), on the thermodynamic (p, ρ, T) properties of a reference high-calorific natural gas mixture with significant ethane and propane content A1 Lozano Martín, Daniel A1 Kipphardt, Heinrich A1 Khanipour, Peyman A1 Tuma, Dirk A1 Horrillo Güemes, Alfonso Jesús A1 Chamorro Camazón, César Rubén K1 Hydrogen-enriched natural gas K1 Gravimetric preparation K1 Single-sinker densimeter K1 High-pressure density K1 Isothermal compressibility K1 Reference equations of state AB Injecting hydrogen into the natural gas grid supports gradual decarbonization. To check the accuracy of equations of state for hydrogen-enriched natural gas mixtures, precise density data from well-characterized reference mixtures are essential. In a prior study, we provided experimental measurements for a natural gas constituted mainly of methane and for two derived hydrogen-enriched mixtures. In the present study, being the second and final part of our investigation, density measurements for a high-calorific natural gas with significant ethane and propane content, along with two hydrogen-enriched variants (10 and 20 mol-% hydrogen) are provided. The mixtures are gravimetrically prepared following ISO 6142-1. Density measurements, conducted with a singlesinker densimeter at temperatures from (260–350) K and pressures up to 20 MPa, are compared with three equations of state: AGA8-DC92, GERG-2008, and an improved GERG-2008. Results indicate that all models perform better for methane-dominant mixtures than for those containing heavier hydrocarbons. PB Elsevier SN 0360-3199 YR 2025 FD 2025 LK https://uvadoc.uva.es/handle/10324/75859 UL https://uvadoc.uva.es/handle/10324/75859 LA eng NO International Journal of Hydrogen Energy, 2025, vol. 140, p. 256-271. NO Producción Científica DS UVaDOC RD 04-jun-2025