RT info:eu-repo/semantics/bachelorThesis
T1 Design of Cooperating Ligands for CH Activation in Direct Arylations of Arenes
A1 Rico Sevillano, Miguel
A2 Universidad de Valladolid. Facultad de Ciencias
K1 Paladio
K1 Activacion C-H
K1 Catalisis
K1 Complejos de paladio
AB The arylation of arenes is an important reaction in synthesis, both first principles andlate stage. Traditionally, this reaction is carried out through the coupling of an aryl halideand an organometallic derivative.Through the application of C–H activation in homogeneous catalysis, a greeneralternative to the traditional reactions is found. Instead of an organometallic compound,the hydrocarbon is reacted directly with the aryl halide. To facilitate the reaction of thegenerally inert C–H bond on a Pd centre, Metal-Ligand Cooperation is required. Theresearch group has focused mainly on the [2,2’-bipyridin]-6(1H)-one ligand. In this workwe synthesize a new ligand that outperforms the previously used one in both rate andselectivity.Metallic complexes with this new ligand were synthesized and stochiometricexperiments were carried out as a preliminary mechanistic study.
YR 2025
FD 2025
LK https://uvadoc.uva.es/handle/10324/78823
UL https://uvadoc.uva.es/handle/10324/78823
LA eng
NO Departamento de Química Física y Química Inorgánica
DS UVaDOC
RD 29-oct-2025