RT info:eu-repo/semantics/article
T1 Synthesis and reactivity of air stable Ni(II) complexes with isocyanides and dialkyldithiophosphate ligands: alkyl transfer and acyclic diaminocarbene formation
A1 Álvarez Miguel, Lucía
A1 Carmen Rodríguez, Clara del
A1 Valle Álvarez, María
A1 Álvarez, Caledonio M.
A1 Martín Álvarez, José Miguel
A1 García Rodríguez, Raúl
A1 Miguel San José, Daniel
K1 Niquel
K1 Carbeno de diamina acíclico
K1 Isocyanides
K1 2303 Química Inorgánica
K1 2303.21-1 Síntesis de Nuevos Materiales a Partir de Compuestos Organometálicos
AB A library of new neutral and cationic Ni(II) complexes containing isocyanide ligands and mono- or dialkyl-dithiophosphate have been prepared and fully characterized. They are subsequently shown to constitute excellent precursors to obtain new families of air stable Ni(II)-based acyclic diaminocarbene (Ni-ADCs) complexes by nucleophilic attack with various alkyl-substituted amines. Remarkably, the ADC is only produced at one of the isocyanide ligands. This was subsequently exploited to obtain an unpredecented dinuclear complex containing a bridging bis-carbene ligand using piperazine.
PB Cambridge University Press
SN 1477-9234
YR 2023
FD 2023
LK https://uvadoc.uva.es/handle/10324/80067
UL https://uvadoc.uva.es/handle/10324/80067
LA eng
NO Dalton Transactions, 2023, vol. 53, n. 36, p. 15101-15112
NO Producción Científica
DS UVaDOC
RD 22-ene-2026