RT info:eu-repo/semantics/article T1 Integral valorization of vine shoots: Production of xylitol, butanol and 2,3-butanediol in a biorefinery context A1 López Linares, Juan Carlos A1 Romero García, Juan Miguel A1 Vidal, Alfonso M. A1 Lucas Yagüe, Susana A1 Coca Sanz, Mónica A1 García Cubero, M.Teresa A1 Romero, Inmaculada A1 Castro, Eulogio K1 Vine shoots K1 Xylitol K1 Butanol K1 Separate hydrolysis and fermentation K1 Simultaneous saccharification and fermentation K1 31 Ciencias Agrarias AB Vine shoots, a carbohydrate-rich lignocellulosic residue, represent a promising feedstock for producing xylitol,butanol, and 2,3-butanediol (2,3-BDO) in an integrated biorefinery. In this work, dilute sulfuric acid steamexplosion (190 ◦C, 5 min, 1.6% w/v H2SO4) was used for the pretreatment of vine shoots. Xylitol was subse-quently produced from the vine shoots hemicellulosic hydrolysate using C. boidinii and C. guilliermondii; whilebutanol and 2,3-BDO were generated from the remaining solid fraction of vine shoots using C. beijerinckii andP. polymyxa, respectively. Furthermore, two process configurations for butanol and 2,3-BDO generation wereevaluated: separate hydrolysis and fermentation (SHF) and simultaneous saccharification and fermentation(SSF), with comparisons conducted at high solids loadings (10% and 15% w/v). As a result, 8.4 g/L xylitol wereachieved from the hemicellulosic fraction with C. boidinii. From the cellulosic fraction, the SHF configuration atthe highest solids loading (15% w/v) yielded 8.8 g/L of butanol (corresponding to 12.4 g/L of total ABE) and13.8 g/L of 2,3-BDO. Therefore, these results demonstrate the potential of vine shoots as a versatile feedstock foran integrated biorefinery PB Elsevier SN 1226-086X YR 2026 FD 2026 LK https://uvadoc.uva.es/handle/10324/83921 UL https://uvadoc.uva.es/handle/10324/83921 LA eng NO Journal of Industrial and Engineering Chemistry, 2026, NO Producción Científica DS UVaDOC RD 06-abr-2026