TY  - JOUR 
AU  - Peñas de Frutos, Marconi Nicolás
AU  - Bartolomé Albistegui, María del Camino
AU  - García Melchor, Max
AU  - Espinet Rubio, Pablo
PY  - 2025
SN  - 0020-1669
UR  - https://uvadoc.uva.es/handle/10324/79560
AB  - In contrast with the previously reported decelerating effect of added L (L = AsPh3) on the Rf/Pf exchange reaction between [Au(Pf)L] and trans-[Rh(Rf)(CO)L2] (Pf = C6F5; Rf = C6F3Cl2-3,5), the Rf/Cl exchange between [AuClL] and trans-[Rh(Rf)(CO)L2] is...
LA  - eng
PB  - American Chemical Society
KW  - Energy
KW  - Gold
KW  - Ligands
KW  - Metals
KW  - Transmetalation
TI  - Opposite effects of added AsPh3 reveal a drastic mechanistic switch in RhI/AuI transmetalations via Rh–Au bonded intermediates
DO  - 10.1021/acs.inorgchem.5c01081
ER  -