TY - JOUR AU - Pozo, Juan del AU - Gioria, Estefanía AU - Casares González, Juan Ángel AU - Álvarez, Rosana AU - Espinet Rubio, Pablo PY - 2015 SN - ISSN: 0276-7333 UR - http://uvadoc.uva.es/handle/10324/21739 AB - The cis/trans isomerization of [PdMeAr(PR3)2] complexes (Ar = C6F5, C6F3Cl2) can take place spontaneously (via dissociation and topomerization, studied experimentally) or catalyzed by ZnMe2. The later mechanism, studied by DFT methods, involves methyl... LA - eng PB - American Chemical Society KW - Chemistry TI - Organometallic nucleophiles and Pd: What Makes ZnMe2 Different? Is Au like Zn? DO - 10.1021/acs.organomet.5b00329 ER -