TY  - JOUR 
AU  - Neves García, Tomaz
AU  - Vélez Blasco, Andrea
AU  - Martínez de Ilarduya Martínez de Ilarduya, Jesús María
AU  - Espinet Rubio, Pablo
PY  - 2018
SN  - 1359-7345
UR  - http://uvadoc.uva.es/handle/10324/32631
AB  - Chiral-diamine catalyzed addition of ZnMe2 to PhC(O)CF2X (in dichloromethane at −30 °C) affords fluorinated alkyl tertiary alcohols in high yield (quantitative for X = H, F, Cl; 84% for X = CF3) and up to 99% ee. These conditions are similarly very...
LA  - eng
PB  - Royal Society of Chemistry
KW  - Química organometálica
KW  - Organometallic chemistry
TI  - Highly enantioselective addition of dimethylzinc to fluorinated alkyl ketones, and the mechanism behind it
DO  - https://doi.org/10.1039/C8CC06358C
ER  -