TY - JOUR AU - Peñas de Frutos, Marconi Nicolás AU - Bartolomé Albistegui, María del Camino AU - García Melchor, Max AU - Espinet Rubio, Pablo PY - 2019 SN - 1521-3757 UR - http://uvadoc.uva.es/handle/10324/38350 AB - By combining kinetic experiments, theoretical calculations and microkinetic modelling, we show that the Pf/Rf (C6F5/C6Cl2F3) exchange between [AuPf(AsPh3)] and trans-[RhRf(CO)(AsPh3)2] does not occur through the typical concerted Pf/Rf... LA - eng PB - Wiley Online Library KW - Gold KW - Oro KW - Bimetallic Catalysis KW - Catálisis bimetálica KW - Functional density calculation KW - Cálculo de densidad funcional KW - Oxidative Addition KW - Adición oxidante KW - Reaction mechanisms KW - Mecanismos de reacción KW - Rhodium KW - Rodio TI - RhIAr/AuIAr′ Transmetalation: A Case of Group Exchange Pivoting on the Formation of M−M′ Bonds through Oxidative Insertion DO - 10.1002/ange.201813419 ER -