TY - JOUR AU - Díez Poza, Carlos AU - Barbero Pérez, María Asunción PY - 2021 SN - 1420-3049 UR - https://uvadoc.uva.es/handle/10324/59213 AB - The regioselective ring opening of epoxy alcohols is an effective method for the synthesis of different types of oxacycles. The 5-exo opening being preferred vs. the 6-endo mode, according to Baldwin rules, the use of silyl-substituted oxiranes has... LA - eng PB - MDPI KW - Química orgánica KW - Organic chemistry KW - Tetrahydropyrans KW - Tetrahydrofurans KW - Cyclization KW - Epoxysilyl alcohols KW - Side reaction KW - Tandem process TI - Influence of the substituents on the opening of silylepoxy alcohols: 5-exo-cyclization towards tetrahydrofurans vs. unexpected side reaction leading to tetrahydropyrans DO - 10.3390/molecules26237386 ER -