TY - JOUR AU - Fernández Moyano, Sara AU - Marcos Ayuso, Guillermo AU - Peñas de Frutos, Marconi Nicolás AU - Espinet Rubio, Pablo PY - 2023 SN - 1359-7345 UR - https://uvadoc.uva.es/handle/10324/59445 AB - 19F NMR monitoring shows that heating trans-[AuIIIRf2I2]− solutions (Rf = C6F3Cl2-3,5) leads to formation of cis-[AuRf2I2]−, [AuRf3I]− and [AuRfI3]−via kinetic competition between isomerization and Rf/I scrambling. The system evolution is driven by... LA - eng PB - Royal Society of Chemistry KW - Isomerización en complejos KW - Isomerization processes TI - Intimate relationship between C–I reductive elimination, aryl scrambling and isomerization processes in Au(iii) complexes DO - 10.1039/D2CC06415D ER -