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    Por favor, use este identificador para citar o enlazar este ítem:http://uvadoc.uva.es/handle/10324/28714

    Título
    ReI(CO)3 complexes with diimine ligands synthesized in situ
    Autor
    Villafañe González, FernandoAutoridad UVA Orcid
    Año del Documento
    2017
    Editorial
    Elsevier
    Descripción
    Producción Científica
    Documento Fuente
    Coordination Chemistry Reviews, 2017, Volume 339, Pages 128-137
    Résumé
    This work covers the coupling reactions of monodentate ligands coordinated to the ‘‘ReI(CO)3” moiety to afford in situ new bidentate diimine ligands. Similar reactions leading to tridentate ligands are also included. The reactions reviewed present evident advantages respect to the usual synthetic methods of these ligands. Besides, choosing the appropriate substituents allows an easy tuning of the properties of the final complexes. Following an approximate chronological order, the formation of bidentate ligands by C-N coupling from a coordinated carbonyl group, from diiminoisoindoline, and the formation of amidino ligands from nitriles are reviewed first. This is followed by the formation of bidentate ligands by C-C coupling, and finally by the formation of tridentate ligands, either by C-C coupling, by B-N coupling, or by using ‘‘click” reactions.
    Materias (normalizadas)
    Química
    coordination chemistry
    Palabras Clave
    Coupling reactions
    Diimines
    In situ synthesis
    Rhenium
    Tridentate ligands
    ISSN
    0010-8545
    Revisión por pares
    SI
    DOI
    10.1016/j.ccr.2017.03.010
    Version del Editor
    https://www.sciencedirect.com/science/article/pii/S001085451730067X
    Propietario de los Derechos
    Elsevier
    Idioma
    eng
    URI
    http://uvadoc.uva.es/handle/10324/28714
    Derechos
    openAccess
    Aparece en las colecciones
    • MIOMeT - Artículos de revista [51]
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    Attribution-NonCommercial-NoDerivatives 4.0 InternationalExcepté là où spécifié autrement, la license de ce document est décrite en tant que Attribution-NonCommercial-NoDerivatives 4.0 International

    Universidad de Valladolid

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