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Mesogenic [Rh(L)4](A) complexes form mesophases with RhI⋯RhI-containing and triphenylene-discotic segregated columns. Effect of RhI⋯RhI interactions and A− = [Au(CN)2]− on hole mobility	326

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Mesogenic [Rh(L)4](A) complexes form mesophases with RhI⋯RhI-containing and triphenylene-discotic segregated columns. Effect of RhI⋯RhI interactions and A− = [Au(CN)2]− on hole mobility	125

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