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Título
Understanding the color change of the solutions of Cp2TiCl upon addition of water
Autor
Año del Documento
2022
Editorial
Wiley
Descripción
Producción Científica
Documento Fuente
Appl Organomet Chem.2023;37:c6979
Abstract
Reduction of red bis (cyclopentadienyl)titanium (IV) dichloride (Cp2TiCl2)with manganese dust in dry THF produces a green solution that turns deepblue upon the addition of traces of water. Mass spectrometric analysis andDFT calculations have been performed to achieve a better understanding ofthe species that may be present after the interaction of water with reducedCp2TiCl2. The deep blue solution provides a handy visual indicator for thequalitative determination of water in THF
Palabras Clave
hydrogen atom transfer reagent
radic
colorimetric indicator
radical chemistry
titanocede
ISSN
0268-2605
Revisión por pares
SI
DOI
Patrocinador
University of Sevilla, Grant/Award Numbers: 2021/00000422, 2020/00001014; University of Almería; Junta de Andalucía; Fondo Europeo de Desarrollo Regional (FEDER), Grant/Award Number: UAL2020-FQM-B1989
Version del Editor
Propietario de los Derechos
© 2022 The Authors.Applied Organometallic Chemistrypublished by John Wiley
Idioma
eng
Tipo de versión
info:eu-repo/semantics/publishedVersion
Derechos
openAccess
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