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Título
Efficient access to polysubstituted tetrahydrofurans by electrophilic cyclization of vinylsilyl alcohols
Autor
Año del Documento
2015
Editorial
Royal Society of Chemistry
Descripción
Producción Científica
Documento Fuente
RSC Adv., 2015, 5, 49541-49551
Abstract
Vinylsilyl alcohols undergo intramolecular cyclization to provide di-, tri- or tetrasubstituted-tetrahydrofurans. The influence of the number and position of substituents in the stereoselectivity of the process has been studied. Moreover, DFT calculations have been performed to get better insight into the influence of the substitution pattern of the vinylsilyl alcohol in the stereoselectivity of the cyclization.
Revisión por pares
SI
Patrocinador
We thank the Ministry of Education, Culture and Sport (MECD) of Spain (CTQ2009-09302) and the “Junta de Castilla y León” (GR170) for financial support. H.B. and A.D.-V. wish to thank the MECD and “Junta de Castilla y León” for doctorate grants.
Propietario de los Derechos
Royal Society of Chemistry
Idioma
eng
Tipo de versión
info:eu-repo/semantics/publishedVersion
Derechos
openAccess
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