RT info:eu-repo/semantics/article
T1 The Rotational Spectrum of Tyrosine
A1 Pérez, Cristóbal
A1 Mata López, Santiago
A1 Cabezas, Carlos
A1 López, Juan Carlos
A1 Alonso Hernández, José Luis
K1 Tirosina
AB In this work neutral tyrosine has been generated in the gas phase by laser ablation of solid samples, and its most abundant conformers characterized through their rotational spectra. Their identification has been made by comparison between the experimental and ab initio values of the rotational and quadrupole coupling constants. Both conformers are stabilized by an O–H•••N hydrogen bond established within the amino acid skeleton chain and an additional weak N–H•••π hydrogen bond. The observed conformers differ in the orientation of the phenolic −OH group.
PB American Chemical Society
YR 2015
FD 2015
LK http://uvadoc.uva.es/handle/10324/22665
UL http://uvadoc.uva.es/handle/10324/22665
LA eng
NO Journal of Physical Chemistry A, 2015, 119 (16), pp 3731–3735
NO Producción Científica
DS UVaDOC
RD 28-abr-2024