RT info:eu-repo/semantics/article
T1 Facile synthesis of a nickel(0) phosphine complex at ambient temperature
A1 Hanf, Schirin
A1 Grell, Toni
A1 Waters, Jessica E.
A1 García Rodríguez, Raúl
A1 Hey-Hawkins, Evamarie
A1 Wright, Dominic Simon
K1 2-piridil
K1 Síntesis
K1 23 Química
AB The reaction of the bis(methoxy)-2-pyridyl-phosphine (MeO)2P(2-py) (1) with [Ni(MeCN)6](BF4)2 leads to the unexpected single-step reduction of NiII and the formation of a tetrahedral nickel(0) complex [{(MeO)2P(2-py-H)}2{(MeO)2P(2-py)}2Ni](BF4)2 (2). The redox activity is probably induced by the decomposition of the tetrafluoroborate anion; NMR spectroscopic studies point towards a fluoride-assisted oxidation of the 2-pyridyl-phosphine ligand, with associated reduction of the metal.
PB Royal Society of Chemistry
SN 1359-7345
YR 2020
FD 2020
LK http://uvadoc.uva.es/handle/10324/43691
UL http://uvadoc.uva.es/handle/10324/43691
LA eng
NO Chemical Communications, 2020, vol. 56, n. 57, p. 7893-7896
NO Producción Científica
DS UVaDOC
RD 14-may-2024