RT info:eu-repo/semantics/article
T1 Coupling the solvent-based CO2 capture processes to the metal water-splitting for hydrogen generation in a semi-continuous system
A1 Río Blandón, Juan Ignacio del
A1 Martín Martínez, Ángel
A1 Bermejo Roda, Maria Dolores
K1 Procesos químicos
K1 Ingeniería química
K1 Renewable and Green Energy
K1 Green hydrogen
K1 CO2-Economy
K1 Metal-water splitting
K1 Hidrógeno verde
K1 CO2-Economía
K1 División metal-agua
K1 3303 Ingeniería y Tecnología Químicas
K1 3308 Ingeniería y Tecnología del Medio Ambiente
AB Hydrogen is considered as the future energy vector. Due to scarceness in materials, obtaining hydrogen from common metals and metallic residues is gaining interest. The present work aims at coupling for the first time solvent-based CO2 capture processes with the hydrogen generation from the metal-water splitting reaction, using common elements such as Al, Zn, Mn and Fe. To do so, a novel semicontinuous facility is developed. In the process, both the CO2-Rich stream (CO2RS) and CO2 Capture-Solvent Lean stream (CO2LS) are considered. The production of H2 increased in the order Al < Mn < Fe < Zn. For pure Al, aqueous NaOH (CO2LS) showed the highest H2 yield, up to 85.5%, while Al chips (residue) showed outstanding performance. The experimental study showed that small particle sizes improve the H2 yield. This technology represents an opportunity for bringing about value-added to CO2 capture by generating at the same time green hydrogen.
PB Elsevier
SN 0360-3199
YR 2023
FD 2023
LK https://uvadoc.uva.es/handle/10324/59200
UL https://uvadoc.uva.es/handle/10324/59200
LA eng
NO International Journal of Hydrogen Energy, 2023, vol. 48, issue 72, p. 27892-27906
NO Producción Científica
DS UVaDOC
RD 23-may-2024