RT info:eu-repo/semantics/article
T1 A bio-based alginate aerogel as an ionic liquid support for the efficient synthesis of cyclic carbonates from CO2 and epoxides
A1 Paninho, Ana B.
A1 Mustapa, Ana Najwa Binti
A1 Mahmudov, Kamran T.
A1 Pombeiro, Armando J. L.
A1 Guedes da Silva, M. Fátima C.
A1 Bermejo Roda, Maria Dolores
A1 Martín Martínez, Ángel
A1 Cocero Alonso, María José
A1 Nunes, Ana V. M.
K1 Carbon dioxide
K1 Epoxy compounds
K1 Alginates
K1 Supercritical fluids
K1 Ionic solutions
K1 Catalysis
K1 Cyclic carbonates
K1 Cycloaddition
K1 Alginate Aerogel
K1 3303 Ingeniería y Tecnología Químicas
AB In this work, the ionic liquid [Aliquat][Cl] was supported into alginate and silica aerogel matrices and applied as a catalyst in the cycloaddition reaction between CO2 and a bio-based epoxide (limonene oxide). The efficiency of the alginate aerogel system is much higher than that of the silica one. The method of wet impregnation was used for the impregnation of the aerogel with [Aliquat][Cl] and a zinc complex. The procedure originated a well-defined thin solvent film on the surface of support materials. Final materials were characterised by Fourier Transform Infrared Spectroscopy, N2 Adsorption–Desorption Analysis, X-ray diffraction, atomic absorption and Field Emission Scanning Microscopy. Several catalytic tests were performed in a high-pressure apparatus at 353.2 K and 4 MPa of CO2.
PB MDPI
SN 2073-4344
YR 2021
FD 2021
LK https://uvadoc.uva.es/handle/10324/59485
UL https://uvadoc.uva.es/handle/10324/59485
LA eng
NO Catalysts, 2021, Vol. 11, Nº. 8, 872
NO Producción Científica
DS UVaDOC
RD 23-may-2024