RT info:eu-repo/semantics/article
T1 Diazo compounds and palladium–aryl complexes: trapping the elusive carbene migratory insertion organometallic products
A1 Villalba de Pando, Francisco
A1 Albéniz Jiménez, Ana Carmen
K1 Chemistry
AB The reactions of Pd–aryl complexes with diazo compounds N2CH–CH=CHPh and N2CHPh allowed us to isolate the organo- metallic products formed right after the migratory insertion of a non-stabilized CHR carbene into the Pd–aryl bond. η3-Allylic and η3-benzylic palladium complexes were formed respectively. This is compelling experimental evidence for the key step in the palla- dium-catalyzed cascade transformations of diazo derivatives leading to multiple C–C or C–X bond formation.
PB Royal Society of Chemistry
SN 1477-9226
YR 2022
FD 2022
LK https://uvadoc.uva.es/handle/10324/60223
UL https://uvadoc.uva.es/handle/10324/60223
LA spa
NO Dalton Trans., 2022, 51, 14847–14851
DS UVaDOC
RD 20-may-2024