TY - JOUR AU - Marcos Ayuso, Guillermo AU - Peñas de Frutos, Marconi Nicolás AU - Gallego Díaz, Ana María AU - García Melchor, Max AU - Martínez de Ilarduya Martínez de Ilarduya, Jesús María AU - Espinet Rubio, Pablo PY - 2022 SN - 0002-7863 UR - https://uvadoc.uva.es/handle/10324/57926 AB - The synthesis of aryl–alkynyl compounds is usually achieved via Sonogashira catalysis, but this is inefficient for fluorinated aryls. An alternative method reported by Shirakawa and Hiyama, using alkynylstannanes and hemilabile PN ligands, works... LA - eng PB - American Chemical Society KW - Catalysis KW - Catálisis KW - Palladium KW - Paladio TI - Problematic ArF–Alkynyl coupling with fluorinated aryls. From partial success with alkynyl stannanes to efficient solutions via mechanistic understanding of the hidden complexity DO - 10.1021/jacs.2c10842 ER -