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dc.contributor.authorCarrasco Fernández, Desiré
dc.contributor.authorPérez Temprano, Mónica H.
dc.contributor.authorCasares González, Juan Ángel 
dc.contributor.authorEspinet Rubio, Pablo 
dc.date.accessioned2016-12-14T13:37:27Z
dc.date.available2016-12-14T13:37:27Z
dc.date.issued2014
dc.identifier.citationOrganometallics, 2014, 33 (13), p. 3540–3545es
dc.identifier.issn0276-7333es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/21728
dc.descriptionProducción Científicaes
dc.description.abstractExperiments on palladium catalyzed cross-coupling of [AuMe(PPh3)] with aryl iodides show that Ar–Ar homocoupling products are the main product or an abundant byproduct of the reaction. The percentage of cross-coupling product is higher for aryls with larger p Hammet parameter. The scrambling of organic groups via bimetallic intermediates explains the formation of these products. This scrambling can be observed and the activation energies partially quantified in some cases using as aryl C6Cl2F3, which is relatively reluctant to coupling.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectCatalystes
dc.titleCross Alkyl-Aryl Versus Homo Aryl-Aryl Coupling in Pdcatalyzed Coupling of Alkyl-Gold(I) and Aryl-X (X = Halide)es
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1021/om500446xes
dc.identifier.publicationissue13es
dc.identifier.publicationtitleAmerican Chemical Societyes
dc.identifier.publicationvolume33es
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad (CTQ2011–25137)es
dc.description.projectJunta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA256U13)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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