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dc.contributor.authorMolina de la Torre, Jesús A.
dc.contributor.authorAlbéniz Jiménez, Ana Carmen 
dc.date.accessioned2016-12-14T19:38:26Z
dc.date.available2016-12-14T19:38:26Z
dc.date.issued2014
dc.identifier.citationChemCatChem, 2014, Volume 6, Issue 12, p. 3547–3552es
dc.identifier.issn1867-3880es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/21742
dc.descriptionProducción Científicaes
dc.description.abstractA bromoalkyl functionalized vinylic addition polynorbornene has been used as an inert new scaffold to support imidazolium salts by straightforward nucleophilic substitution using different imidazoles ImR (R=Me, mesityl, 2,6-iPr2C6H3). These polymers, VA-PNB-(CH2)4ImRBr, are precursors of N-heterocyclic carbenes which are useful as heterogeneous organocatalysts. The polymeric carbenes have been tested in two model reactions: The synthesis of saturated esters from α,β-unsaturated aldehydes and the conjugate umpolung reaction of α,β-unsaturated aldehydes for the synthesis of γ-butyrolactones. The supported catalyst (R=mesityl) is fully recyclable and can be recovered as an imidazolium salt and stored for further use.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectChemistryes
dc.subjectCatalystses
dc.titleN-Heterocyclic Carbenes Supported on Vinylic Addition Polynorbornene: A Recyclable and Recoverable Organocatalystes
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1002/cctc.201402767es
dc.identifier.publicationissue12es
dc.identifier.publicationtitleChemCatChemes
dc.identifier.publicationvolume6es
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad (CTQ2013-48406-P)es
dc.description.projectMinisterio de Economía, Industria y Competitividad (CTQ2010-18901/BQU)es
dc.description.projectJunta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA302U13)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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