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dc.contributor.authorLentijo, S.
dc.contributor.authorExpósito Fuertes, José Emilio
dc.contributor.authorAullón, Gabriel
dc.contributor.authorMiguel, Jesús A.
dc.contributor.authorEspinet Rubio, Pablo 
dc.date.accessioned2016-12-15T11:55:26Z
dc.date.available2016-12-15T11:55:26Z
dc.date.issued2014
dc.identifier.citationDalton Transactions, 2014, 43, p. 10885-10897es
dc.identifier.issn1477-9226es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/21767
dc.descriptionProducción Científicaes
dc.description.abstractThe perylene derivatives 3-isocyanoperylene (Per–N≡C) (4a) and N-(2,5-di-tert-butylphenyl)- 9-isocyano-perylene-3,4-dicarboximide (PMI–N≡C) (4b) were prepared and used to synthesize gold complexes [AuX(CNR)] (X = C6F5 (5a,b), C6F4-OnBu-p (6b)). The reaction of 5b and 6b with HNEt2 led the carbene complexes [AuX{C(NEt2)(NHR)}] (7b, 8b), respectively. The molecular structure of complexes 7b, 8b have been determined by X-ray diffraction analysis showing intermolecular π–stacking of the perylene groups and C6F5 rings, and no Au···Au interactions. The derivative compounds [M(CO)5(CNR)] (M = Cr (9a,b), Mo (10a,b) or W (11a,b)) and trans-[Pd(CNR)2(C6F3Cl2)2] (12a,b) were also prepared. All complexes exhibit fluorescence associated to the perylene fragment with emission quantum yields, in solution at room temperature, in the range 0.05 – 0.93 and emission lifetimes ~ 4 ns. DFT calculations were performed of the absorption spectra of the ligands Per–N≡C and PMI–N≡C, and representative complexes [Au(C6F5)(CNR)], [Cr(CO)5(CNR)], showing a perylene-dominated intraligand π–π*emissive state, from the HOMO and LUMO orbitals of the perylene chromophore, but with significantly different absorption maxima by influence of the metal fragment, particularly significant in the Per–N≡C derivatives.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectChemistryes
dc.titleHighly fluorescent complexes with 3-isocyanoperylene and N-(2,5-di-tert-butylphenyl)-9-isocyano-perylene- 3,4-dicarboximidees
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1039/C4DT01016Ges
dc.identifier.publicationtitleDalton Transactionses
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad (CTQ2011-2513)es
dc.description.projectMinisterio de Economía, Industria y Competitividad (CTQ2011-23862-C02)es
dc.description.projectJunta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA302U13)es
dc.description.projectGeneralitat de Catalunya (grant 2009SGR-1459)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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