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dc.contributor.authorHerrero Villar, Manuel 
dc.contributor.authorNúñez Carrero, Karina Carla
dc.contributor.authorGallego Castro, Raúl
dc.contributor.authorMerino Senovilla, Juan Carlos 
dc.contributor.authorPastor Barajas, José María 
dc.date.accessioned2017-11-27T12:27:57Z
dc.date.available2017-11-27T12:27:57Z
dc.date.issued2016
dc.identifier.citationEuropean Polymer Journal (2016) 75. p.125-141es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/27379
dc.descriptionProducción Científicaes
dc.description.abstractIn an effort to understand the influence of the shape and area of the nanoclay type used in the in situ polymerization process, two different types of clays (fibrillar and laminar) were employed to obtain nanocomposites. The preliminary results demonstrated that a needlelike shaped clay promotes higher molar mass and better mechanical properties compared with laminar clay. The ultra-high molecular weight of sepiolite/nanocomposites introduces significant problems with processability. Therefore, a new method of polymerization was designed to include two significant changes. The first change was related to the use of a non-isothermal temperature profile and the second to the addition of an additional amount of non-anchored co-catalyst leading to materials with higher fluidity.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherElsevieres
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.titleControl of Molecular weight and polydispersity in polyethylene/needle-like shaped clay nanocomposites obtained by in situ polymerization with metallocene catalystses
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holderMinisterio de Economía y Competitividades
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía y Competitividades
dc.rightsAttribution 4.0 International


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