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dc.contributor.authorÁlvarez González, Celedonio Manuel 
dc.contributor.authorBarbero San Juan, Héctor
dc.contributor.authorFerrero, Sergio
dc.contributor.authorMiguel San José, Daniel 
dc.date.accessioned2018-03-20T13:03:18Z
dc.date.available2018-03-20T13:03:18Z
dc.date.issued2016
dc.identifier.citationJournal of Organic Chemistry, 2016, 81 (14), pp 6081–6086es
dc.identifier.issn0022-3263es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/29161
dc.descriptionProducción Científicaes
dc.description.abstractSymmetric meso-tetraarylporphyrins bearing phenanthrene, pyrene, and corannulene moieties in meta positions have been synthesized in a straightforward procedure under microwave irradiation by quadruple Suzuki–Miyaura reactions. Their 1H NMR spectra showed the typical pattern of four atropisomers distributed according to their statistical ratio not properly separable due to their fast isomerization. Their ability to bind buckminsterfullerene has been tested with the whole mixture, and different behaviors have been found, α4 isomer corannulene-substituted porphyrins being the best hosts in the family.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.classificationTetraaryl Porphyrinses
dc.titleSynergistic Effect of Tetraaryl Porphyrins Containing Corannulene and Other Polycyclic Aromatic Fragments as Hosts for Fullerenes. Impact of C60 in a Statistically Distributed Mixture of Atropisomerses
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1021/acs.joc.6b00454es
dc.relation.publisherversionhttps://pubs.acs.org/doi/abs/10.1021/acs.joc.6b00454es
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad (Project CTQ 2013-41067-P)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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