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dc.contributor.authorMartín Ruiz, Blanca
dc.contributor.authorPérez Ortega, Ignacio
dc.contributor.authorAlbéniz Jiménez, Ana Carmen 
dc.date.accessioned2018-09-09T16:26:19Z
dc.date.available2018-09-09T16:26:19Z
dc.date.issued2018
dc.identifier.citationOrganometallics, 2018, Vol. 37, p. 1074-1085es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/31462
dc.description.abstractA large variety of α-(pentafluorophenylmethyl)benzylic palladium complexes with different ligands have been synthesized and char- acterized. Multinuclear NMR spectroscopic data allow to determine the σ-or η3-benzylic nature of the complexes in solution. The adoption of either coordination mode is a function of the number of ligands coordinated to palladium and, remarkably, the presence of bulky phosphines favors the adoption of a bidentate η3-benzylic mode and palladium pentacoordinated complexes. Experimental data and DFT calculations indicate that this five- coordination could alleviate the steric hindrance of two cis bulky phosphines. The benzylic complexes show a rich fluxional behavior that involves both ligand exchange and σ- to η3-benzylic interconversion.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.subjectChemistryes
dc.subjectOrganometallic Chemistryes
dc.subject.classificationPalladiumes
dc.subject.classificationBenzyl complexeses
dc.titleBenzylic Complexes of Palladium(II): Bonding modes and Penta- coordination for Steric Reliefes
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1021/acs.organomet.8b00065es
dc.relation.publisherversionhttps://pubs.acs.org/doi/abs/10.1021/acs.organomet.8b00065
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad (SGPI, grant CTQ2016-80913-P)


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