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dc.contributor.authorGarcía Romero, Álvaro
dc.contributor.authorPlajer, Alex J.
dc.contributor.authorÁlvarez Miguel, Lucía
dc.contributor.authorBond, Andrew D.
dc.contributor.authorWright, Dominic Simon
dc.contributor.authorGarcía Rodríguez, Raúl 
dc.date.accessioned2018-12-11T11:37:25Z
dc.date.issued2018
dc.identifier.citationChemistry A European Journal, 2018, Volume 24, Issue 64, Pages 17019-17026es
dc.identifier.issn0947-6539es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/33405
dc.descriptionProducción Científicaes
dc.description.abstractPostfunctionalization of the aluminate anion [EtAl(6‐Me‐2‐py)3]− (1) (2‐py=2‐pyridyl) with alkoxide ligands can be achieved by the selective reactions of the lithium salt 1 Li with alcohols in the appropriate stoichiometry. This method can be used to introduce 3‐ and 4‐py functionality in the form of 3‐ and 4‐alkoxymethylpyridyl groups, while maintaining the integrity of the aluminate framework, thereby giving entry to new supramolecular chemistry. Chirality can be introduced either by using a chiral alcohol as a reactant or by the stepwise reaction of 1 Li with two different nonchiral alcohols. The latter route has allowed the synthesis of a rare example of a chiral‐at‐aluminium aluminate.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.classificationQuímica supramoleculares
dc.subject.classificationSupramolecular Chemistryes
dc.titlePostfunctionalization of Tris(pyridyl) Aluminate Ligands: Chirality, Coordination, and Supramolecular Chemistryes
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doihttps://doi.org/10.1002/chem.201803342es
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/chem.201803342es
dc.peerreviewedSIes
dc.description.embargo2019-11-16es
dc.description.lift2019-11-16
dc.description.projectMinisterio de Economía, Industria y Competitividad - Agencia Estatal de Investigación (AEI)es
dc.description.projectEuropean Social Fund (ESF)es
dc.description.projectRamón y Cajal contract (RG-R, RYC-2015–19035)es
dc.description.projectThe Leverhulme Trust (Grant for D.S.W.and R.G.-R.)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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