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Título
Accurate experimental (p, ρ, T) data for the introduction of hydrogen into the natural gas grid: Thermodynamic characterization of the nitrogen-hydrogen binary system from 240 K to 350 K and pressures up to 20 MPa
Año del Documento
2017
Editorial
American Chemical Society Publications
Documento Fuente
J. Chem. Eng. Data 2017, 62, 4310-4326
Abstract
The experimental density data of the binary system nitrogen-hydrogen available at the time of the development of the equation of state for natural gases and related mixtures, GERG-2008, were limited to hydrogen contents higher than 0.15 (amount-of-substance fraction) and temperatures above 270 K. This work provides accurate experimental (p, ρ, T) data for three binary mixtures of nitrogen and hydrogen: (0.95 N2 + 0.05 H2), (0.90 N2 + 0.10 H2), and (0.50 N2 + 0.50 H2) at temperatures of (240, 250, 260, 275, 300, 325, and 350) K, thus extending the range of available experimental data to low hydrogen contents and low temperatures. The density measurements were performed by using a single-sinker densimeter with magnetic suspension coupling at pressures up to 20 MPa. Experimental data were compared with the corresponding densities calculated from the GERG-2008 and the AGA8-DC92 equations of state. The relative deviations of the experimental data from both equations of state were within the estimated uncertainty value of the equations. Therefore, the experimental data agree very well with the values estimated from the equations. The virial coefficients B(T,x), C(T,x), and D(T,x) as well as the second interaction virial coefficient for the nitrogen-hydrogen binary system were also calculated from the experimental data set at temperatures from (240 to 350) K. The resulting values agree with those from literature.
Materias (normalizadas)
Termodinámica
Palabras Clave
Density
Equation of state
Hydrogen
Natural gas
Nitrogen
Single-sinker densimeter
ISSN
0021-9568
Revisión por pares
SI
Patrocinador
MEC ENE2013-47812-R
European Commission’s ENG54
Junta de Castilla y León VA035U16
European Commission’s ENG54
Junta de Castilla y León VA035U16
Idioma
eng
Derechos
openAccess
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