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dc.contributor.authorMartín Ruiz, Blanca
dc.contributor.authorPérez Ortega, Ignacio
dc.contributor.authorAlbéniz Jiménez, Ana Carmen 
dc.date.accessioned2018-09-09T16:22:01Z
dc.date.available2018-09-09T16:22:01Z
dc.date.issued2018
dc.identifier.citationOrganometallics, 2018, vol. 37, p. 1665-1670es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/31461
dc.description.abstractThe adoption of a pseudoallylic (η3) form makes palladium benzylic derivatives a class of stabilized palladium alkyls that can undergo β-H elimination reactions in a more controlled way. α- (Pentafluorophenylmethyl)benzyl palladium complexes have been studied and they decompose by β-H elimination to give palladium hydrides that, depending on the auxil- iary ligands can: a) transmetalate to another palladium atom and, by reductive elimina- tion, give hydrogenated products; this process is favored for a combination of bridging ligands (i.e halogens) and low coordinating ligands. b) Be used as a hydride source and get trapped by a diene to give palladium allylic derivatives. The presence of carbon mon- oxide does not induce a β-H elimination reactions and only CO insertion into the Pd- benzyl bond to give acyl derivatives is observed.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.subjectChemistryes
dc.subjectOrganometallic Chemistryes
dc.subject.classificationPalladiumes
dc.subject.classificationBenzyl complexeses
dc.subject.classificationHydrideses
dc.subject.classificationTransmetalationes
dc.titleα-Substituted Benzylic Complexes of Palladium(II) as Precursors of Palladium Hydrideses
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1021/acs.organomet.8b00066es
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/acs.organomet.8b00066
dc.peerreviewedSIes
dc.description.projectMINECO (SGPI, grant CTQ2016-80913-P)es


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