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dc.contributor.authorPérez Iglesias, María 
dc.contributor.authorLozano Lavilla, Olmo
dc.contributor.authorCasares González, Juan Ángel 
dc.date.accessioned2019-07-16T07:51:32Z
dc.date.available2019-07-16T07:51:32Z
dc.date.issued2019
dc.identifier.citationOrganometallics, 2019, vol. 38, n. 4. p. 739-742es
dc.identifier.issn0276-7333es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/37014
dc.descriptionProducción Científicaes
dc.description.abstractThe copper compound [Cu(C6Cl2F3)(tht)]4 (1) (tht: tetrahydrothiophene) is an excellent catalyst for the trans- to cis- isomerization of complexes [PdAr2(tht)2](Ar: fluoroaryl) and also for the exchange of aryls between those palladium complexes. Herein, we also communicate the synthesis and characterization of 1, and some of its derivatives. The x-ray structure of 1 shows a linear chain of copper atoms, supported by fluoroaryl rings. The NMR 19F-DOSY study indicates that this structure is preserved in solution although in equilibrium with other species.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherACS Publicationses
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subject.classificationCatalystses
dc.subject.classificationCatalizadoreses
dc.subject.classificationAryles
dc.subject.classificationAriloes
dc.subject.classificationPalladium Complexeses
dc.subject.classificationComplejos de Paladioes
dc.subject.classification[Cu(C6Cl2F3)(tht)]4es
dc.title[Cu(C6Cl2F3)(tht)]4: An Extremely Efficient Catalyst for the Aryl Scrambling between Palladium Complexeses
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holder© 2019 American Chemical Societyes
dc.identifier.doihttps://doi.org/10.1021/acs.organomet.8b00885es
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/acs.organomet.8b00885es
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad ( project CTQ2016-80913-P)es
dc.description.projectJunta de Castilla y León (Projects VA051P17 and VA062G18)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones


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