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dc.contributor.authorYang, Eric S.
dc.contributor.authorPlajer, Alex J.
dc.contributor.authorGarcía Romero, Álvaro
dc.contributor.authorBond, Andrew D.
dc.contributor.authorRonson, Tanya K.
dc.contributor.authorÁlvarez González, Celedonio Manuel 
dc.contributor.authorGarcía Rodríguez, Raúl 
dc.contributor.authorColebatch, Annie Louise
dc.contributor.authorWright, Dominic Simon
dc.date.accessioned2019-12-17T13:20:14Z
dc.date.available2019-12-17T13:20:14Z
dc.date.issued2019
dc.identifier.citationChemistry: A European Journal, 2019, vol. 25, n. 61. p. 14003-14009es
dc.identifier.issn1521-3765es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/39917
dc.descriptionProducción Científicaes
dc.description.abstractThe systematic assembly of supramolecular arrangements is a persistent challenge in modern coordination chemistry, especially where further aspects of complexity are concerned, as in the case of large molecular mixed‐metal arrangements. One targeted approach to such heterometallic complexes is to engineer metal‐based donor ligands of the correct geometry to build 3D arrangements upon coordination to other metals. This simple idea has, however, only rarely been applied to main group metal‐based ligand systems. Here, we show that the new, bench‐stable tris(3‐pyridyl)stannane ligand PhSn(3‐Py)3 (3‐Py=3‐pyridyl) provides simple access to a range of heterometallic SnIV/transition metal complexes, and that the presence of weakly coordinating counter anions can be used to build discrete molecular arrangements involving anion encapsulation. This work therefore provides a building strategy in this area, which parallels that of supramolecular transition metal chemistry.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWiley Online Libraryes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subject.classificationEncapsulationes
dc.subject.classificationEncapsulaciónes
dc.subject.classificationCoordination polymerses
dc.subject.classificationPolimeros de coordinaciónes
dc.subject.classificationSupramolecular chemistryes
dc.subject.classificationQuímica supramoleculares
dc.titleA Tris(3‐pyridyl)stannane as a Building Block for Heterobimetallic Coordination Polymers and Supramolecular Cageses
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holder© 2019 Wiley-VCHes
dc.identifier.doi10.1002/chem.201903498es
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201903498es
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad - Agencia Estatal de Investigación - Fondo Social Europeo (Ramon y Cajal contract RG‐R, RYC‐2015‐19035)es
dc.description.projectMinisterio de Ciencia, Innovación y Universidades - Agencia Estatal de Investigación - FEDER - Unión Europea (project PGC2018‐096880‐A‐I00))es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones


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