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dc.contributor.author | Hanf, Schirin | |
dc.contributor.author | Grell, Toni | |
dc.contributor.author | Waters, Jessica E. | |
dc.contributor.author | García Rodríguez, Raúl | |
dc.contributor.author | Hey-Hawkins, Evamarie | |
dc.contributor.author | Wright, Dominic Simon | |
dc.date.accessioned | 2020-11-26T12:20:19Z | |
dc.date.available | 2020-11-26T12:20:19Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Chemical Communications, 2020, vol. 56, n. 57, p. 7893-7896 | es |
dc.identifier.issn | 1359-7345 | es |
dc.identifier.uri | http://uvadoc.uva.es/handle/10324/43691 | |
dc.description | Producción Científica | es |
dc.description.abstract | The reaction of the bis(methoxy)-2-pyridyl-phosphine (MeO)2P(2-py) (1) with [Ni(MeCN)6](BF4)2 leads to the unexpected single-step reduction of NiII and the formation of a tetrahedral nickel(0) complex [{(MeO)2P(2-py-H)}2{(MeO)2P(2-py)}2Ni](BF4)2 (2). The redox activity is probably induced by the decomposition of the tetrafluoroborate anion; NMR spectroscopic studies point towards a fluoride-assisted oxidation of the 2-pyridyl-phosphine ligand, with associated reduction of the metal. | es |
dc.format.mimetype | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject.classification | 2-piridil | es |
dc.subject.classification | Síntesis | es |
dc.title | Facile synthesis of a nickel(0) phosphine complex at ambient temperature | es |
dc.type | info:eu-repo/semantics/article | es |
dc.rights.holder | © Royal Society of Chemistry | es |
dc.identifier.doi | 10.1039/D0CC02142C | es |
dc.relation.publisherversion | https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc02142c#!divAbstract | es |
dc.identifier.publicationfirstpage | 7893 | es |
dc.identifier.publicationissue | 57 | es |
dc.identifier.publicationlastpage | 7896 | es |
dc.identifier.publicationtitle | Chemical Communications | es |
dc.identifier.publicationvolume | 56 | es |
dc.peerreviewed | SI | es |
dc.description.project | Ministerio de Ciencia, Innovación y Universidades (PGC2018-096880-A-I00. AEI / FEDER, UE) | es |
dc.identifier.essn | 1364-548X | es |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.type.hasVersion | info:eu-repo/semantics/acceptedVersion | es |
dc.subject.unesco | 23 Química | es |
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